R is equal to NAkB, where NA is the Avogadro number and kB is Boltzmann's constant. The ideal gas law for one mole of gas is thus pV = RT . The molar gas constant is most accurately found by measuring the speed of sound in argon.
References
The CRC Handbook of Chemistry and Physics , 81st edition, 2000-2001
The theory of thermodynamics , J R Waldram, CUP, 1985